一、导师简介：

   

 

 

李龙, 男，教授，硕导， longwzu1990@wzu.edu.cn

2012.9-2018.6博士就读于厦门大学化学化工学院（导师：叶龙武教授）。2018.6-2019.6在厦大做研究助理。2019.6-2020.6在德国马尔堡大学做博士后研究（导师：Eric Meggers 教授）。于2020.9受BETVlCTOR手机登录绿色通道资助进入BETVlCTOR手机登录化学材料学院工作。研究兴趣主要在于有机方法学研究，以通讯作者，第一作者身份在Angew. Chem. Int. Ed.，ACS Catal.，Chem. Sci.等国际著名刊物上发表正式论文25篇，论文被引用700余次（H-index: 16, 其中2篇研究论文单篇被引>100次, 部分文章被选为front cover, ESI高被引论文。

 

二、研究方向：

1. 炔烃转化

2. 新型手性催化剂的设计与应用

3. 不对称催化合成手性功能分子

 

三、发表文章：

 

1.       Auxiliary-Free Remote Dearomatizative Nitrenoid Transfer for Enantioselective Construction of Spirolactams. Bo-Han Zhu, Wen-Ting Guo, Qing Sun, * Peng-Cheng Qian, * Long-Wu Ye, and Long Li*,  Adv. Synth. & Catal.2022, 364, 314.

2.       Claisen Rearrangement Triggered by Brønsted Acid-Catalyzed Alkyne Alkoxylation. Yao-Hong Yan, Long Li,* Long-Wu Ye,* Synlett 2022, accepted.

3.       Recent Progress in the Gold-Catalyzed Annulations of Ynamides with Isoxazole   Derivatives via α-Imino Gold Carbenes. Long Li,* Wen-Feng Luo, Long-Wu Ye,* Synlett 2021, 32, 1303.

4.       Regio- and diastereoselective synthesis of trans-3,4-diaryldihydrocoumarins via metal-free [4+2] annulation of ynamides with o-hydroxybenzyl alcohols. Wen-Feng Luo, Long-Wu Ye, Long Li* and Peng-Cheng Qian*, Chem. Commun., 2021, 57, 5032.

5.       Claisen rearrangement triggered by transition metal-catalyzed alkyne alkoxylation. Chong-Yang Shi, Long Li,* Wei Kang, Yan-Xin Zheng, Long-Wu Ye,* Coord. Chem. Rev. 2021, 446, 214131.

6.       Completing Pyridine-2,6-bis(oxazoline) with Cyclometalated Ligand for Modulated Asymmetric Transition Metal Catalysis. Long Li,† Feng Han,† Xin Nie,† Yubiao Hong, Sergei Ivlev and Eric Meggers,* Angew. Chem. Int. Ed. 2020, accepted.

7.       Zinc-Catalyzed Alkyne Oxidation/C−H Functionalization: Highly Site-Selective Synthesis of Versatile Isoquinolones and β-Carbolines. Long Li,† Bo Zhou,† Yong-Heng Wang, Chao Shu, Yi-Fei Pan, Xin Lu,* Long-Wu Ye,* Angew. Chem. Int. Ed. 2015, 54, 8   245.

8.       Metal-Free Alkene Carbooxygenation Following Tandem Intramolecular Alkoxylation/Claisen Rearrangement: Stereocontrolled Access to Bridged [4.2.1] Lactones. Long Li, Xin-Qi Zhu, Ying-Qi Zhang, Hao-Zhen Bu, Peng Yuan, Jinyu Chen, Jingyi Su, Xianming Deng, Long-Wu Ye,* Chem. Sci. 2019, 10, 3123-3129.

9.       Generation of Gold Carbenes in Water: Efficient Intermolecular Trapping of the α-Oxo Gold Carbenoids by Indoles and Anilines. Long Li,† Chao Shu,† Bo Zhou, Yong-Fei Yu, Xin-Yu Xiao, Long-Wu Ye,* Chem. Sci. 2014, 5, 4057.

10.    Reversal of Regioselectivity in Catalytic Arene-Ynamide Cyclization: Direct Synthesis of Valuable Azepino[4,5-b]indoles and β–Carbolines and DFT Calculations. Long Li, Xiu-Mei Chen, Ze-Shu Wang, Bo Zhou, Xin Liu, Xin Lu,* Long-Wu Ye,* ACS Catal. 20    17, 7, 4004.

11.    Recent Advances in Transition-Metal-Catalyzed Reactions of Alkynes with Isoxazoles. Long Li,† Tong-De Tan,† Ying-Qi Zhang, Xin Liu, Long-Wu Ye,* Org. Biomol. Chem. 2017, 15, 8483.

12.    Yttrium-Catalyzed Tandem Intramolecular Hydroalkoxylation/Claisen Rearrangement: Efficient Synthesis of Medium-Sized Lactams. Bo Zhou, Long Li, Xin-Qi Zhu, Juan-Zhu Yan, Yi-Lin Guo, Long-Wu Ye,* Angew. Chem. Int. Ed. 2017, 56, 4015.

13.    Flexible and Practical Synthesis of 3-Oxyindoles through Gold-Catalyzed Intermolecular Oxidation of o-Ethynylanilines. Chao Shu, Long Li, Xin-Yu Xiao, Yong-Fei Yu, Yi-Fan Ping, Jin-Mei Zhou, Long-Wu Ye,* Chem. Commun. 2014, 50, 8689.

14.    Gold-Catalyzed Intermolecular Oxidation of Chiral Homopropargyl Sulfonamides: A Reliable Access to Enantioenriched Pyrrolidin-3-ones. Chao Shu, Long Li, Yong-Fei Yu, Shuang Jiang, Long-Wu Ye,* Chem. Commun. 2014, 50, 2522.

15.    Divergent Synthesis of N-Heterocycles via Controllable Cyclization of Azido-Diynes Catalyzed by Copper and Gold. Wen-Bo Shen, Qing Sun, Long Li, Xin Liu, Bo Zhou, Juan-Zhu Yan, Xin Lu,* Long-Wu Ye,* Nat. Commun. 2017, 8, 1748.

 

三、获奖情况：

1.  2018第十三届福建省自然科学优秀学术论文一等奖 （全省共33位）

2.  2018厦门大学优秀毕业论文奖

3.  2015年，唐敖庆奖学金 （全国共42位）

4.  2014年，教育部硕士国家奖学金